Thermally/hydrolytically stable covalent organic frameworks from a rigid macrocyclic host.
نویسندگان
چکیده
Two new 2D COFs were synthesized from triformylcyclotrianisylene, which show not only thermal stability but also hydrolytic stability. CTV-COF-1 with smaller pore size stored a high hydrogen level of 1.3 wt% at low pressure, while CTV-COF-2 with larger pore size showed superior carbon dioxide uptake, up to 250 cm(3) g(-1) at 298 K and 50 bar.
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ورودعنوان ژورنال:
- Chemical communications
دوره 50 7 شماره
صفحات -
تاریخ انتشار 2014